The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium II salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon.
Palladium Catalyzed Oxidation of Hydrocarbons
The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J.
Tsuji [Accounts Chem. Heck [Adv. B Inorganic Chemistry of Palladium. C Organometallic Chemistry of Palladium. Oxidation of Monoolefins. C Production of Esters. D Production of Ethers and Acetals in Alcohols.
E Formation of CarbonCarbon Bonds. Reactions of Acetylenes. C Nonoxidative Reactions. Create Alert. Share This Paper.click here
Speciated Hydrocarbon Conversion on a Fresh Pd/Rh Three-Way Catalyst
Tables and Topics from this paper. Citations Publications citing this paper. Hobart , Joseph S. Yu-Feng Liang , Ning Jiao. Dudkina , Mikhail Khrizanforov.
Haloalkynes: a powerful and versatile building block in organic synthesis. Wanqing Wu , Huanfeng Jiang. Short diastereoselective synthesis of the C1-C13 AB spiroacetal and CC28 fragments CD spiroacetal of spongistatin 1 and 2 through double chain-elongation reactions.
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